The reaction of $\mathrm{Q}$ with $\mathrm{PhSNa}$ yields an organic compound (major product) that gives positive Carius test on treatment with${\mathrm{Na}}_2{\mathrm{O}}_2$ followed by addition of ${\mathrm{BaCl}}_2.$ The correct option $\left(\mathrm{s}\right)$ for $\mathrm{Q}$ is(are)